N-(2-Bromobenzyl)-N′-(2-pyridyl)benzene-1,2-diamine

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N-(2-Bromo­benz­yl)-N′-(2-pyrid­yl)benzene-1,2-diamine

In the title compound, C(18)H(16)BrN(3), mol-ecules are linked into dimers by co-operative inter-molecular N-H⋯N hydrogen bonding. Only one N-H group is involved in hydrogen bonding. The planes of the pyridine and bromo-phenyl rings are twisted by 61.49 (3) and 79.11 (8)°, respectively, from the plane of the central phenyl ring.

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[μ-N,N′-Bis(2-amino­eth­yl)ethane-1,2-diamine-κ4 N 1,N 1′:N 2,N 2′]bis­{[N,N′-bis­(2-amino­eth­yl)ethane-1,2-diamine-κ4 N,N′,N′′,N′′′]cadmium} tetra­kis­(perchlorate)

The centrosymmetric dinuclear cadmium title complex, [Cd(2)(C(6)H(18)N(4))(3)](ClO(4))(4), was obtained by the reaction of N,N'-bis-(2-amino-eth-yl)ethane-1,2-diamine (trien) with Cd(NO(3))(2)·4H(2)O and sodium perchlorate in methanol. The Cd(II) cation is coordinated by four N atoms of a non-bridging trien ligand and by two N atoms of a bridging trien ligand in a slightly distorted octa-hedral...

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N 2,N 2,N 6,N 6-Tetra­kis(2,3,4,5,6-penta­fluoro­benzo­yl)pyridine-2,6-diamine

The title compound, C(33)H(3)F(20)N(3)O(4), is a highly fluorinated organic imide that was isolated as an unexpected product from the reaction of 2,6-diamino-pyridine with 2,3,4,5,6-penta-fluoro-benzoyl chloride in a 1:2 molar ratio. The mol-ecule is located on a twofold axis and one of its symmetry-independent 2,3,4,5,6-penta-fluoro-benzoyl groups is disordered over two sets of sites, the occu...

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Diaqua­[N,N′-bis­(2-pyridylmethyl­ene)propane-1,3-diamine]manganese(II) dibromide–aqua­bromido[N,N′-bis­(2-pyridylmethyl­ene)propane-1,3-diamine]manganese(II) bromide–dibromido[N,N′-bis­(2-pyridylmethyl­ene)propane-1,3-diamine]manganese(II) (1/2/1)

There are three different Mn(II) complexes in the asymmetric unit of the title compound, [Mn(C(15)H(16)N(4))(H(2)O)(2)]Br(2)·2{[MnBr(C(15)H(16)N(4))(H(2)O)]Br}·[MnBr(2)(C(15)H(16)N(4))]. In the neutral complex, the Mn(2+) ion is six-coordinated in a distorted octa-hedral environment by four N atoms of the tetra-dentate ligand N,N'-bis-(2-pyridylmethyl-ene)propane-1,3-diamine (bppd) and two brom...

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N,N′-Bis(2-thienylmethyl­ene)benzene-1,4-diamine

The Schiff base, C(16)H(12)N(2)S(2), has been synthesized by refluxing an ethano-lic solution of thio-phene-2-carbaldehyde and benzene-1,4-diamine. The center of the benzene ring is located on a crystallographic center of inversion. The dihedral angle between the benzene and thio-phene rings is 63.6 (1)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809039130